Hexaflumuron | 86479-06-3

Hexaflumuron Properties

Melting point	197-199°
Density	1.4069 (estimate)
vapor pressure	5.9 x l0^-5 Pa (25 °C)
storage temp.	Sealed in dry,2-8°C
solubility	DMF: 10 mg/ml,DMSO: 10 mg/ml,DMSO:PBS(pH 7.2) (1:2): 0.3 mg/ml
Water Solubility	2.7 x l0^-22 mg l^-1 (18 °C)
pka	8.54±0.46(Predicted)
BRN	8168725
Stability	Stable. Incompatible with strong oxidizing agents.
InChIKey	RGNPBRKPHBKNKX-UHFFFAOYSA-N
CAS DataBase Reference	86479-06-3(CAS DataBase Reference)
FDA UNII	4GW50R449T
Pesticides Freedom of Information Act (FOIA)	Hexaflumuron
EPA Substance Registry System	Hexaflumuron (86479-06-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS09

Signal word

Warning

Hazard statements

H410

Precautionary statements

Hazard Codes

Risk Statements

Safety Statements

RIDADR

UN 3077

WGK Germany

2

RTECS

CV3800000

HazardClass

9

PackingGroup

III

Toxicity

LD50 oral in rat: > 5gm/kg

NFPA 704

	0
3		0

Hexaflumuron price More Price(11)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	37902	Hexaflumuron PESTANAL?, analytical standard	86479-06-3	100mg	$132	2024-03-01	Buy
Sigma-Aldrich	37902	Hexaflumuron PESTANAL	86479-06-3	100mg-r	$103	2021-12-16	Buy
Cayman Chemical	18598	Hexaflumuron ≥95%	86479-06-3	50mg	$57	2024-03-01	Buy
Cayman Chemical	18598	Hexaflumuron ≥95%	86479-06-3	100mg	$98	2024-03-01	Buy
Cayman Chemical	18598	Hexaflumuron	86479-06-3	25mg	$32	2024-03-01	Buy

Product number	Packaging	Price	Buy
37902	100mg	$132	Buy
37902	100mg-r	$103	Buy
18598	50mg	$57	Buy
18598	100mg	$98	Buy
18598	25mg	$32	Buy

Hexaflumuron Chemical Properties,Uses,Production

Description

Hexaflumuron is a termite pesticide, the first “reduced-risk pesticide” registered by the US EPA. Unlike traditional methods, it is regurgitated at the nest – allowing it to be applied in environmentally-friendly baiting stations, rather than liquid chemical barriers. It is an Insect Growth Regulator (IGR), acting on the synthesis of chitin, the main component of the exoskeleton. Its clearance and metabolism is slow, allowing for a high degree of bioconcentration. It can be used against subterranean termite colonies for wood structures including buildings, fences, trees, decking, and more, to control Reticulitermes, Coptotermes, and Heterotemes.

mechanism of action

Hexaflumuron is an insect growth regulator (IGR) that works by inhibiting the insect’s growth. It interferes with chitin synthesis, which termites need to form a new exoskeleton.
Hexaflumuron is part of a pest monitoring system and is used selectively only in baiting stations where termite activity is present and only when the activity continues. Termites are social insects that share food and feeding sites. Foraging termites recruit nestmates to feeding sites by leaving a pheromone trail to the site, allowing the entire nest to feed on the bait containing hexaflumuron.
Pest control operators use hexaflumuron as part of aboveground and underground baiting systems. They place it in a tamper-resistant bait station where foraging termites consume it.

uses

Hexaflumuron is used to control subterranean termite colonies. It is used in above-ground and inground bait stations as part of termite monitoring and control programs. Target sites include buildings, fences, utility poles, decking, landscape plantings, trees, and other wood structures that can be damaged by termite foraging and feeding. Hexaflumuron products are used only by licensed pest management professionals.
Hexaflumuron is registered by the U.S. Environmental Protection Agency (EPA) for use as termite bait. End-use termite bait formulations containing hexaflumuron are registered and sold in more than 25 countries including Australia, Brazil, China, France, Japan, Spain, and the United States. Formulations are packaged into bait stations for in-ground installation around structures and in stations for above-ground installation.

toxicity

Animals
Hexaflumuron has a low toxicity when fed to rats in laboratory studies. See boxes on LD50,Laboratory Testing box and Toxicity Categories.
Laboratory tests indicate hexaflumuron is nonirritating to the skin and eyes of rabbits.
Humans
Scientists do not consider hexaflumuron a skin sensitizer.
Hexaflumuron toxicity

reference

http://msdssearch.dow.com/PublishedLiteratureDOWCOM/dh_091b/0901b8038091b652.pdf?filepath=productsafety/pdfs/noreg/233-00932.pdf&fromPage=GetDoc
http://npic.orst.edu/factsheets/hexgen.pdf
http://www.doityourselftermitecontrol.com/chemical-termite-treatments.html
https://www.caymanchem.com/product/18598
http://dissemination.echa.europa.eu/Biocides/ActiveSubstances/1314-18/1314-18_Assessment_Report.pdf
https://npic.orst.edu/factsheets/archive/hextech.pdf
https://www.epestcontrol.com/images/Products/labels/hexaflumeroninfosheet.pdf

Description

Hexaflumuron is a benzoylphenyl urea-type insecticide and is the common name for N-(((3,5- dichloro-4-(1,1,2,2-tetrafluoro-ethoxy)phenyl)amino)carbonyl)-2,6-difluorobenzamide. It the active ingredient in several termite control products registered to Dow AgroSciences LLC, a wholly owned subsidiary of The Dow Chemical Company. Hexaflumuron was the first active ingredient to be registered with the U.S. Environmental Protection Agency (EPA) as a reduced-risk pesticide. A reduced-risk pesticide is one that the EPA believes has low impact on human health, low toxicity to non-target organisms, and low potential for groundwater contamination. Hexaflumuron’s mode of action is to inhibit chitin synthesis. Termites produce chitin to form or maintain an exoskeleton.
Hexaflumuron is an odorless white solid that is formulated into low-concentration solid briquettes that are contained within tamper-resistant bait stations. Formulated hexaflumuron briquettes contain about 0.5% of the active ingredient, with the balance comprised almost entirely of cellulose.
Hexaflumuron formulations have been marketed under the trade names RECRUIT® AG termite bait, SHATTER*termite bait, SENTRI*TECH, RECRUTE® Pro, Hex-Pro(TM) Termite Baiting System, Sentricon(TM) IG Termite Bait, Sentricon(TM) AG Termite Bait, Sentricon® Termite Colony Elimination System.

Chemical Properties

White solid or powder. The commercial product may be an emulsifiable concentrate.

Uses

Hexaflumuron is an benzoylphenylurea based chitin synthesis inhibitor used against Ephestia figulilella.

Uses

Hexaflumuron is used for the control of larvae of Lepidoptera, Coleoptera, Homoptera and Diptera on top fruit, cotton and vegetables. It is also used in forestry.

Definition

ChEBI: An N-acylurea that is urea in which a hydrogen attached to one of the nitrogens is replaced by a 2,6-difluorobenzoyl group, while a hycrogen attached to the other nitorgen is replaced by a 3,5-dichloro-4-(1,1,2,2-tetrafluoroethoxy)phenyl group.

Potential Exposure

Hexaflumuron is a benzoyl urea insecti cide, termiticide and insect growth regulator (IGR) that inhi bits an insect’s growth through chitin synthesis, which termites need to form an exoskeleton. It is used to impregnate termite bait. Worldwide, there are more than 20 suppliers/ manufacturers; most are in the United States Not currently registered for agricultural use in some EU countries.

Metabolic pathway

Although there is limited dormation on the metabolism of hexaflumuron in the open literature, there is a useful summary provided by Dow Agrosciences (Anon). Metabolic pathways are shown in Scheme 1.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz ardous material, Technical Name Required.

Degradation

Hexaflumuron is stable to hydrolysis at pH 5.0 (25°C) over 33 days and hydrolysis at pH 7.0 is slow (6% in 33 days). However, hydrolysis at pH 9.0 was more rapid (DT₅₀ 21-23 days). Alkaline hydrolysis followed two separate routes, namely the formation of 2,6-difluorobenzoic acid (2) and 3,5-dichloro-4-( 1,1,2,2-tetrafluoroethoxy)phenylurea (3) and a slower reaction to form 2,6-difluorobenzamide (4) and 3,5-dichloro-4-( 1,1,2,2- tetrafluoroethoxy)anilhe (5).
When [¹⁴C-aniline] and [¹⁴C-benzoyl]hexaflumuron were irradiated in sterile aqueous buffer at pH 5, the DT₅₀ was approximately 6.3 days. The major photolysis product from the benzoyl label was 4 (96% of the applied radioactivity) and from the aniline label was 3,5-dichloro-4- hydroxyaniline (6). The latter comprised 35% of the applied radioactivity and a further 60% was released as ¹⁴CO₂ from the aniline label indicating extensive ring-opening.

Incompatibilities

Decomposes in temperatures above 275 C. Irritating or toxic fumes or gases in a fire

Waste Disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved land fill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Hexaflumuron Preparation Products And Raw materials

Raw materials

Flufenoxuron 4-(1,1,2,2-TETRAFLUOROETHOXY)ANILINE Sulfolane Potassium fluoride Phenyl isocyanate

2,6-Difluorobenzamide 2,6-Difluorobenzoyl isocyanate Chlorfluazuron PHOSGENE Cyanhydric acid

Oxalyl chloride

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Preparation Products

Hexaflumuron Suppliers

Global( 233)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22968	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49391	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569266 15319487004	1015@dideu.com	China	2263	58
Masteam Bio-tech Co., Ltd.	+86-15200345168 +86-15200345168	bruce.lei@masteam.com	CHINA	153	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12471	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	6000	58
SIMAGCHEM CORP	+86-13806087780	sale@simagchem.com	China	17367	58

Supplier	Advantage
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Hubei xin bonus chemical co. LTD	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Shaanxi Dideu Medichem Co. Ltd	58
Masteam Bio-tech Co., Ltd.	58
Hebei Mojin Biotechnology Co., Ltd	58
Hebei Yanxi Chemical Co., Ltd.	58
SIMAGCHEM CORP	58

View Lastest Price from Hexaflumuron manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-09-06	Hexaflumuron 86479-06-3	US $0.00-0.00 / KG	1KG	99%	500000kg	Hebei Guanlang Biotechnology Co., Ltd.
2023-07-25	Hexaflumuron 86479-06-3	US $200.00 / Kg/Drum	1KG	95%;98%	20tons/month	Hebei Yanxi Chemical Co., Ltd.
2023-01-31	hexaflumuron 86479-06-3	US $0.00 / Kg/Bag	1Kg/Bag	99%	20ton	Hebei Mojin Biotechnology Co., Ltd

Hexaflumuron
86479-06-3
US $0.00-0.00 / KG
99%
Hebei Guanlang Biotechnology Co., Ltd.

Hexaflumuron
86479-06-3
US $200.00 / Kg/Drum
95%;98%
Hebei Yanxi Chemical Co., Ltd.

hexaflumuron
86479-06-3
US $0.00 / Kg/Bag
99%
Hebei Mojin Biotechnology Co., Ltd

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1-(3,5-dichloro-4-(1,1,2,2-tetrafluoroethoxy)phenyl)-3-(2,6-difluorobenzoyl) 6-difluoro-)- ai3-29832 benzamide,n-(((3,5-dichloro-4-(1,1,2,2-tetrafluoroethoxy)phenyl)amino)carbonyl hexafluoron xrd473 CONSOL CONSULT CONSULT(R) HEXAFLUMURON N-[3,5-DICHLORO-4-(1,1,2,2-TETRAFLUOROETHOXY)PHENYLCARBAMOYL]-2,6-DIFLUOROBENZAMIDE hexaflumuron (bsi,iso) 1-[3,5-dichloro-4-(1,1,2,2-tetrafluoroethoxy) phenyl]-3-(2,6-difuorobenzoyl) urea Trueno DE-473 Hexafluron N-(((3,5-dichloro-4-(1,1,2,2-tetrafluoroethoxy)phenyl)amino)carbonyl)-2,6-difluorobenzamide Hexaflumuron E.C. OMS-3031 BenzaMide,N-[[[3,5-dichloro-4-(1,1,2,2-tetrafluoroethoxy)phenyl]aMino]carbonyl]-2,6-difluoro- Hexaflumuron 0 Hexaflumuron 250mg [86479-06-3] Hexafluron Consult DE-473 Consult(TM Hexaflumuron Solution, 1000ppm Hexaflumuron @100 μg/mL in Methanol Hexaflumuron@1000 μg/mL in Acetonitrile HexaflumuronSolution,100mg/L,1ml Hexaflumuron Standard Hexaflumuron Solution in Methanol, 100μg/mL α-D-Glucopyranose 1-phosphate Fluoride bell urea Hexaflumuron Solution in Metha Hexaflumuron Solution in Acetonitrile Hexaflumuron Solution in Methanol 86479-06-3 367-38-5 C16H8ClF6N2O3 C16H8Cl2F6N2O3 INSECTICIDE